Optimal electron doping of a C60 monolayer on Cu(111) via interface reconstruction
Journal
Physical Review Letters
Journal Volume
104
Journal Issue
3
Pages
036103-1 - 036103-4
Date Issued
2010
Author(s)
Jeng, H.T.
Cheng, C.-M.
Lin, C.-H.
Xiao, X.
Zhao, A.
Zhang, X.
Xu, G.
Shi, X.Q.
Van Hove, M.A.
Hsue, C.-S.
Tsuei, K.-D.
Abstract
We demonstrate the charge state of C60 on a Cu(111) surface can be made optimal, i.e., forming C60(3-) as required for superconductivity in bulk alkali-doped C60, purely through interface reconstruction rather than with foreign dopants. We link the origin of the C60(3-) charge state to a reconstructed interface with ordered (4x4) 7-atom vacancy holes in the surface. In contrast, C60 adsorbed on unreconstructed Cu(111) receives a much smaller amount of electrons. Our results illustrate a definitive interface effect that affects the electronic properties of molecule-electrode contact.
Type
journal article