Nb S3: A unique quasi-one-dimensional conductor with three charge density wave transitions
Journal
Physical Review B
Journal Volume
95
Journal Issue
3
Pages
035110-1 - 035110-14
Date Issued
2017
Author(s)
Zybtsev, S.G.
Pokrovskii, V.Ya.
Nasretdinova, V.F.
Zaitsev-Zotov, S.V.
Pavlovskiy, V.V.
Odobesco, A.B.
Lin, Y.G.
Zupanič, E.
Van Midden, H.J.P.
Šturm, S.
Tchernychova, E.
Prodan, A.
Bennett, J.C.
Mukhamedshin, I.R.
Chernysheva, O.V.
Menushenkov, A.P.
Loginov, V.B.
Loginov, B.A.
Titov, A.N.
Abdel-Hafiez, M.
Abstract
We review the features of the charge density wave (CDW) conductor NbS3 (phase II) and include several additional results from transport, compositional, and structural studies. Particularly, we highlight three central results: (1) In addition to the previously reported CDW transitions at TP1=360K and TP2=150K, a third CDW transition occurs at a much higher temperature TP0≈620-650K; evidence for the nonlinear conductivity of this CDW is presented. (2) We show that the CDW associated with the TP2 transition arises from S vacancies acting as donors. Such a CDW transition has not been observed before. (3) We demonstrate the exceptional coherence of the TP1 CDW at room temperature. The effects of uniaxial strain on the CDW transition temperature and transport are reported.
Publisher
American Physical Society
Type
journal article