https://scholars.lib.ntu.edu.tw/handle/123456789/575727
標題: | Linking the Dynamic Chemical State of Catalysts with the Product Profile of Electrocatalytic CO2 Reduction | 作者: | Wang J Tan H.-Y Zhu Y Chu H Chen H.M. HAO MING CHEN |
關鍵字: | Carbon dioxide; Electrocatalysts; Electrolysis; Electrolytic reduction; Metal drawing; Morphology; Thermodynamics; Atomic defects; Chemical state; CO2 reduction; Critical links; Electrocatalytic; Electrochemical reductions; Structural feature; Copper | 公開日期: | 2021 | 來源出版物: | Angewandte Chemie - International Edition | 摘要: | The promoted activity and enhanced selectivity of electrocatalysts is commonly ascribed to specific structural features such as surface facets, morphology, and atomic defects. However, unraveling the factors that really govern the direct electrochemical reduction of CO2 (CO2RR) is still very challenging since the surface state of electrocatalysts is dynamic and difficult to predict under working conditions. Moreover, theoretical predictions from the viewpoint of thermodynamics alone often fail to specify the actual configuration of a catalyst for the dynamic CO2RR process. Herein, we re-survey recent studies with the emphasis on revealing the dynamic chemical state of Cu sites under CO2RR conditions extracted by in situ/operando characterizations, and further validate a critical link between the chemical state of Cu and the product profile of CO2RR. This point of view provides a generalizable concept of dynamic chemical-state-driven CO2RR selectivity that offers an inspiration in both fundamental understanding and efficient electrocatalysts design. ? 2021 Wiley-VCH GmbH |
URI: | https://www.scopus.com/inward/record.uri?eid=2-s2.0-85104544518&doi=10.1002%2fanie.202017181&partnerID=40&md5=5581405f03aa6776f599302df407e639 https://scholars.lib.ntu.edu.tw/handle/123456789/575727 |
ISSN: | 14337851 | DOI: | 10.1002/anie.202017181 |
顯示於: | 化學系 |
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