https://scholars.lib.ntu.edu.tw/handle/123456789/576753
標題: | Asymmetric Benzotrithiophene-based hole transporting materials provide high-efficiency perovskite solar cells | 作者: | Budiawan W Lai K.-W Karuppuswamy P Jadhav T.S Lu Y.-A Ho K.-C Wang P.-C Chang C.-C Chu C.-W. KUO-CHUAN HO |
關鍵字: | Crystallinity; Efficiency; Hole mobility; Molecules; Perovskite; Synthesis (chemical); Aromatic cores; Candidate materials; Good stability; High-efficiency; Hole-transporting materials; Power conversion efficiencies; Small molecules; Triphenyl amines; Perovskite solar cells | 公開日期: | 2020 | 卷: | 12 | 期: | 26 | 起(迄)頁: | 29143-29152 | 來源出版物: | ACS Applied Materials and Interfaces | 摘要: | In this study, we synthesized a series of small-molecule benzotrithiophenes (BTTs) and used them as hole transporting materials (HTMs) in perovskite solar cells (PSCs). The asymmetric benzo[2,1-b:-3,4-b':5,6-b']trithiophene unit was used as the central core to which were appended various donor groups, namely, carbazole (BTT-CB), thieno thiophene (BTT-FT), triphenylamine (BTT-TPA), and bithiophene (BTT-TT). The extended aromatic core in the asymmetric BTT provided full planarity, thereby favoring intermolecular π-stacking and charge transport. The physical, optical, and electrical properties of these small-molecule HTMs are reported herein. BTT-TT displayed good crystallinity and superior hole mobility, when compared with those of the other three HTMs, and formed smooth and uniform surfaces when covering the perovskite active layer. Accordingly, among the devices prepared in this study, a PSC incorporating BTT-TT as the HTM achieved the highest power conversion efficiency (18.58%). Moreover, this BTT-TT-containing device exhibited good stability after storage for more than 700 h. Thus, asymmetric BTTs are promising candidate materials for use as small-molecule HTMs in PSCs. Copyright ? 2020 American Chemical Society. |
URI: | https://www.scopus.com/inward/record.uri?eid=2-s2.0-85087918168&doi=10.1021%2facsami.0c02204&partnerID=40&md5=edffaa26ca3ddc74b7514124b2c9805e https://scholars.lib.ntu.edu.tw/handle/123456789/576753 |
ISSN: | 19448244 | DOI: | 10.1021/acsami.0c02204 |
顯示於: | 化學工程學系 |
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