https://scholars.lib.ntu.edu.tw/handle/123456789/576814
標題: | Diels–Alder Conversion of Acrylic Acid and 2,5-Dimethylfuran to para-Xylene Over Heterogeneous Bi-BTC Metal-Organic Framework Catalysts Under Mild Conditions | 作者: | Yeh J.-Y Chen S.S Li S.-C Chen C.H Shishido T Tsang D.C.W Yamauchi Y Li Y.-P YI-PEI LI KEVIN CHIA-WEN WU |
關鍵字: | Carboxylic acids; Organic pollutants; Organometallics; Xylene; 2-methylfuran; Acrylic acids; Bio-based; Furan derivatives; Para-xylene; Reaction energy barriers; Reaction strategies; Metal-Organic Frameworks | 公開日期: | 2021 | 卷: | 60 | 期: | 2 | 起(迄)頁: | 624-629 | 來源出版物: | Angewandte Chemie - International Edition | 摘要: | The heterogeneous metal-organic framework Bi-BTC successfully catalyzed the synthesis of para-xylene from bio-based 2,5-dimethylfuran and acrylic acid in a promising yield (92 %), under relatively mild conditions (160 °C, 10 bar), and with a low reaction-energy barrier (47.3 kJ mol?1). The proposed reaction strategy also demonstrates a remarkable versatility for furan derivatives such as furan and 2-methylfuran. ? 2020 Wiley-VCH GmbH |
URI: | https://www.scopus.com/inward/record.uri?eid=2-s2.0-85097022231&doi=10.1002%2fanie.202013061&partnerID=40&md5=f0b51d4135338feb14963ead94bc16e8 https://scholars.lib.ntu.edu.tw/handle/123456789/576814 |
ISSN: | 14337851 | DOI: | 10.1002/anie.202013061 |
顯示於: | 化學工程學系 |
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