A Resource utilization method for volatile organic compounds emission from the semiconductor industry: Selective catalytic oxidation of isopropanol to acetone Over Au/α-Fe2O3 nanosheets
Journal
Applied Catalysis B: Environmental
Journal Volume
275
Date Issued
2020
Author(s)
Zhang H
Abstract
We prepare α-Fe2O3 nanosheet supported 0.38, 0.81, and 1.36 wt% Au (average particle size = 4.0 nm) nanocatalysts, and investigate their performance and mechanism for the selective catalytic oxidation of isopropanol to acetone. In the presence of 1.2 vol% isopropanol and 40 vol% O2, 1.36 wt% Au/α-Fe2O3 exhibits excellent catalytic performance, due to its moderate acidic sites and better redox properties, with acetone selectivity and yield being as high as 99% and 95% at 220 oC, respectively. In addition to acetone, little propylene, acetic acid, acetaldehyde, methyl vinyl ketone, 2-butanone, isopropyl ether, isopropyl acetate, 3-penten-2-one, isopropyl acrylate, isopropyl propionate, and 2, 4-dimethylfuran are detected. The possible reaction mechanism is proposed for the selective catalytic oxidation of isopropanol to acetone over the present catalysts. We believe the present selective catalytic oxidation method, rather than the traditional complete catalytic oxidation method, provides an alternative and economic method for VOCs emissions control. ? 2020 Elsevier B.V.
Subjects
Acetone; Hematite; Nanocatalysts; Nanosheets; Oxidation; Particle size; Semiconductor device manufacture; Volatile fatty acids; Volatile organic compounds; Average particle size; Catalytic performance; Emissions control; Methyl vinyl ketones; Reaction mechanism; Resource utilizations; Selective catalytic oxidation; Semiconductor industry; Catalytic oxidation
SDGs
Type
journal article