https://scholars.lib.ntu.edu.tw/handle/123456789/598288
標題: | Understanding the catalytic activity of microporous and mesoporous zeolites in cracking by experiments and simulations | 作者: | Li S.-C Lin Y.-C Li Y.-P. YI-PEI LI |
關鍵字: | Catalytic activity;Density functional theory;Mesoporous materials;Zeolite | 公開日期: | 2021 | 卷: | 11 | 期: | 9 | 來源出版物: | Catalysts | 摘要: | Porous zeolite catalysts have been widely used in the industry for the conversion of fuel-range molecules for decades. They have the advantages of higher surface area, better hydrothermal stability, and superior shape selectivity, which make them ideal catalysts for hydrocarbon cracking in the petrochemical industry. However, the catalytic activity and selectivity of zeolites for hydrocarbon cracking are significantly affected by the zeolite topology and composition. The aim of this review is to survey recent investigations on hydrocarbon cracking and secondary reactions in micro-and mesoporous zeolites, with the emphasis on the studies of the effects of different porous environments and active site structures on alkane adsorption and activation at the molecular level. The pros and cons of different computational methods used for zeolite simulations are also discussed in this review. ? 2021 by the authors. Licensee MDPI, Basel, Switzerland. |
URI: | https://www.scopus.com/inward/record.uri?eid=2-s2.0-85114951486&doi=10.3390%2fcatal11091114&partnerID=40&md5=a3ea506bd108d0ee575462f29cc22967 https://scholars.lib.ntu.edu.tw/handle/123456789/598288 |
ISSN: | 20734344 | DOI: | 10.3390/catal11091114 |
顯示於: | 化學工程學系 |
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