https://scholars.lib.ntu.edu.tw/handle/123456789/611512
標題: | Reversible CO binding enables tunable CO/H2 and CO/N2 separations in metal-organic frameworks with exposed divalent metal cations | 作者: | Bloch E.D. Hudson M.R. Mason J.A. Chavan S. Crocell? V. Howe J.D. Lee K. Dzubak A.L. Queen W.L. Zadrozny J.M. Geier S.J. Lin L.-C. Gagliardi L. Smit B. Neaton J.B. Bordiga S. Brown C.M. Long J.R. LI-CHIANG LIN |
關鍵字: | Adsorbents;Adsorption isotherms;Binding energy;Carbon monoxide;Cobalt compounds;Crystalline materials;Distillation;Electronic structure;Gas adsorption;Iron compounds;Manganese;Nickel;Positive ions;Spectroscopy;Zinc;Adsorbent regeneration;Cryogenic distillations;Divalent metal cations;Electronic structure calculations;Ideal adsorbed solution theories (IAST);Industrial gas mixtures;Metal organic framework;Structure determination;Metals;adsorbent;carbon monoxide;carbonyl derivative;cobalt derivative;hydrogen;iron derivative;magnesium derivative;manganese derivative;metal ion;nickel complex;nitrogen;zinc derivative;adsorption;article;binding affinity;calculation;chemical binding;chemical composition;chemical interaction;chemical structure;crystal structure;density functional theory;dissociation;distillation;gas;infrared spectroscopy;structure analysis;temperature dependence | 公開日期: | 2014 | 卷: | 136 | 期: | 30 | 起(迄)頁: | 10752-10761 | 來源出版物: | Journal of the American Chemical Society | 摘要: | Six metal-organic frameworks of the M2(dobdc) (M = Mg, Mn, Fe, Co, Ni, Zn; dobdc4- = 2,5-dioxido-1,4-benzenedicarboxylate) structure type are demonstrated to bind carbon monoxide reversibly and at high capacity. Infrared spectra indicate that, upon coordination of CO to the divalent metal cations lining the pores within these frameworks, the C-O stretching frequency is blue-shifted, consistent with nonclassical metal-CO interactions. Structure determinations reveal M-CO distances ranging from 2.09(2) ? for M = Ni to 2.49(1) ? for M = Zn and M-C-O angles ranging from 161.2(7)° for M = Mg to 176.9(6)° for M = Fe. Electronic structure calculations employing density functional theory (DFT) resulted in good agreement with the trends apparent in the infrared spectra and crystal structures. These results represent the first crystallographically characterized magnesium and zinc carbonyl compounds and the first high-spin manganese(II), iron(II), cobalt(II), and nickel(II) carbonyl species. Adsorption isotherms indicate reversible adsorption, with capacities for the Fe, Co, and Ni frameworks approaching one CO per metal cation site at 1 bar, corresponding to loadings as high as 6.0 mmol/g and 157 cm3/cm3. The six frameworks display (negative) isosteric heats of CO adsorption ranging from 52.7 to 27.2 kJ/mol along the series Ni > Co > Fe > Mg > Mn > Zn, following the Irving-Williams stability order. The reversible CO binding suggests that these frameworks may be of utility for the separation of CO from various industrial gas mixtures, including CO/H2 and CO/N2. Selectivities determined from gas adsorption isotherm data using ideal adsorbed solution theory (IAST) over a range of gas compositions at 1 bar and 298 K indicate that all six M2(dobdc) frameworks could potentially be used as solid adsorbents to replace current cryogenic distillation technologies, with the choice of M dictating adsorbent regeneration energy and the level of purity of the resulting gases. ? 2014 American Chemical Society. |
URI: | https://www.scopus.com/inward/record.uri?eid=2-s2.0-84905251111&doi=10.1021%2fja505318p&partnerID=40&md5=7936cce1dda0f4359ce1774e280ac872 https://scholars.lib.ntu.edu.tw/handle/123456789/611512 |
DOI: | 10.1021/ja505318p |
顯示於: | 化學工程學系 |
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