https://scholars.lib.ntu.edu.tw/handle/123456789/612098| Title: | Activation of Hydrogen and Hydrogenation Catalysis by a Borenium Cation | Authors: | Farrell, Jeffrey M. Hatnean, Jillian A. Stephan, Douglas W. JEFFREY M. FARRELL |
Issue Date: | 2012 | Journal Volume: | 134 | Journal Issue: | 38 | Start page/Pages: | 15728-15731 | Source: | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | Abstract: | The readily prepared borenium salt [(IiPr 2)(BC 8H 14)][B(C 6F 5) 4] (2) [IiPr 2 = C 3H 2(NiPr) 2] is shown to activate H 2 heterolytically in the presence of tBu 3P. Compound 2 also acts as a catalyst for the metal-free hydrogenation of imines and enamines at room temperature. ? 2012 American Chemical Society. |
URI: | https://www.scopus.com/inward/record.uri?eid=2-s2.0-84866712340&doi=10.1021%2fja307995f&partnerID=40&md5=784e7ba2386fcb1d99b30ba2fe105251 https://scholars.lib.ntu.edu.tw/handle/123456789/612098 |
DOI: | 10.1021/ja307995f | metadata.dc.subject.other: | Enamines; Hydrogenation catalysis; Room temperature; Hydrogen; Hydrogenation; boron derivative; cation; enamine; hydrogen; imine; article; catalysis; hydrogenation; room temperature |
| Appears in Collections: | 化學系 |
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