https://scholars.lib.ntu.edu.tw/handle/123456789/616350
標題: | Bandgap Shrinkage and Charge Transfer in 2D Layered SnS2 Doped with V for Photocatalytic Efficiency Improvement | 作者: | Shelke A.R. Chen K.-H. Chen L.-C. LI-CHYONG CHEN |
公開日期: | 2022 | 卷: | 18 | 期: | 2 | 來源出版物: | Small | 摘要: | Effects of electronic and atomic structures of V-doped 2D layered SnS2 are studied using X-ray spectroscopy for the development of photocatalytic/photovoltaic applications. Extended X-ray absorption fine structure measurements at V K-edge reveal the presence of V-O and V-S bonds which form the intercalation of tetrahedral O-V-S sites in the van der Waals (vdW) gap of SnS2 layers. X-ray absorption near-edge structure (XANES) reveals not only valence state of V dopant in SnS2 is ≈4+ but also the charge transfer (CT) from V to ligands, supported by V Lα,β resonant inelastic X-ray scattering. These results suggest V doping produces extra interlayer covalent interactions and additional conducting channels, which increase the electronic conductivity and CT. This gives rapid transport of photo-excited electrons and effective carrier separation in layered SnS2. Additionally, valence-band photoemission spectra and S K-edge XANES indicate that the density of states near/at valence-band maximum is shifted to lower binding energy in V-doped SnS2 compare to pristine SnS2 and exhibits band gap shrinkage. These findings support first-principles density functional theory calculations of the interstitially tetrahedral O-V-S site intercalated in the vdW gap, highlighting the CT from V to ligands in V-doped SnS2. © 2021 Wiley-VCH GmbH |
URI: | https://www.scopus.com/inward/record.uri?eid=2-s2.0-85119503822&doi=10.1002%2fsmll.202105076&partnerID=40&md5=aee7acdf37081c0dba89b20d49bb68bd https://scholars.lib.ntu.edu.tw/handle/123456789/616350 |
ISSN: | 16136810 | DOI: | 10.1002/smll.202105076 | SDG/關鍵字: | Binding energy;Calculations;Charge transfer;Density functional theory;Extended X ray absorption fine structure spectroscopy;IV-VI semiconductors;Ligands;Light absorption;Shrinkage;Tin compounds;Valence bands;Van der Waals forces;X ray absorption;X ray absorption near edge structure spectroscopy;X ray scattering;Band-gap shrinkage;Bandgap shrinkage;Density-functional-theory;Inelastic X-rays scatterings;Photocatalytic efficiency;Resonant inelastic X-ray scattering;V-doped 2d layered SnS 2;Van der Waal;X-ray absorption near-edge structure;X-ray absorptions;Energy gap |
顯示於: | 凝態科學研究中心 |
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