https://scholars.lib.ntu.edu.tw/handle/123456789/633008
標題: | Using recoverable sulfurized magnetic biochar for active capping to remediate multiple heavy metal contaminated sediment | 作者: | Hsu, Che Jung Cheng, Yung Hua Chung, Adrienne Huang, Ying Pin Ting, Yu HSING-CHENG HSI |
關鍵字: | Active capping | Heavy metal | Magnetic biochar | Sediment remediation | 公開日期: | 1-一月-2023 | 出版社: | ELSEVIER SCI LTD | 卷: | 316 | 期: | Pt 1 | 來源出版物: | Environmental Pollution | 摘要: | Due to anthropogenic activities, heavy metals are discharged into the hydrosphere and deposit onto the sediment. Heavy metals remobilize through physical disturbance and change in environmental conditions, posing a risk to environments and human health. Among several remediation methods, active layer capping is considered to be more feasible due to its financial and technical advantages; however, its long-term effects remain unknown. To overcome this problem, this work applied a novel, recoverable amendment, sulfurized magnetic biochar (SMBC), to remediate multiple heavy metal (Cu, Ni, Zn, Cr, Hg, and MeHg) contaminated sediment. Physiochemical characterization shows magnetite (Fe3O4) crystalline in both magnetic biochar (MBC) and SMBC, with such characteristics resulting in a greater surface area (324.9 and 346.3 m2/g) than BC (39.6 m2/g) and SBC (65.0 m2/g). FeS crystalline was also observed in SMBC, which plays an important role in controlling heavy metal release from sediment. Microcosm experiments indicated the effectiveness of SMBC in lowering aquatic Cu, Ni, Zn, Hg, and MeHg releases was significantly greater than the other three biochar materials. Notably, the recovery of SMBC by magnetism was 87%, demonstrating the exceptional recoverability of SMBC from seawater and sediment. Based on its robust capability in lowering Cu, Ni, Zn, Hg, and MeHg release and excellent recoverability from seawater and sediment, this technique represents a practical alternative to conventional approaches for heavy metal immobilization from sediment. |
URI: | https://scholars.lib.ntu.edu.tw/handle/123456789/633008 | ISSN: | 02697491 | DOI: | 10.1016/j.envpol.2022.120555 |
顯示於: | 環境工程學研究所 |
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