Conformational Preferences and the Phase Stability of Fullerene Hexa-adducts
Journal
Chemistry, an Asian journal
Journal Volume
11
Journal Issue
14
Pages
2011
Date Issued
2016-07-20
Author(s)
Abstract
Molecular conformation and the assembly structure determine the spatial arrangements of the constituent units and the functions of a molecule. Although, fullerene hexa-adducts (FHAs) have been known as functional materials with great versatility, their conformational preferences and phase stability remain a complicate issue. By choosing bithiophene (T2 ) and dodecyl bithiophene (C12 T2 ) as the peripheral units of FHA, and using microscopic, scattering and diffraction characterizations, our study reveals how the intramolecular interaction and environmental stimulus affects the conformational preferences and phase stability of FHAs.
Subjects
conformation; conjugated molecule; fullerene; phase stability; self-organization
SDGs
Type
journal article