https://scholars.lib.ntu.edu.tw/handle/123456789/640127
標題: | Demonstration of a Gel-Polymer Electrolyte-Based Electrochromic Device Outperforming Its Solution-Type Counterpart in All Merits: Architectural Benefits of CeO2 Quantum Dot and Nanorods | 作者: | Silori, Gaurav Kumar Thoka, Subashchandrabose KUO-CHUAN HO |
關鍵字: | CeO nanofillers 2 | flexible electrochromic devices | gel-polymer electrolyte | haze analysis | oxygen vacancies | quantum dot and nanorod | stress−strain | surface defects | 公開日期: | 31-一月-2024 | 卷: | 16 | 期: | 4 | 來源出版物: | ACS Applied Materials and Interfaces | 摘要: | For years, solution-type electrochromic devices (ECDs) have intrigued researchers’ interest and eventually rendered themselves into commercialization. Regrettably, challenges such as electrolyte leakage, high flammability, and complicated edge-encapsulation processes limit their practical utilization, hence necessitating an efficient alternate. In this quest, although the concept of solid/gel-polymer electrolyte (SPE/GPE)-based ECDs settled some issues of solution-type ECDs, an array of problems like high operating voltage, sluggish response time, and poor cycling stability have paralyzed their commercial applicability. Herein, we demonstrate a choreographed-CeO2-nanofiller-doped GPE-based ECD outperforming its solution-type counterpart in all merits. The filler-incorporated polymer electrolyte assembly was meticulously weaved through the electrospinning method, and the resultant host was employed for immobilizing electrochromic viologen species. The filler engineering benefits conceived through the tuned shape of CeO2 nanorod and quantum dots, along with the excellent redox shuttling effect of Ce3+/Ce4+, synchronously yielded an outstanding class of GPE, which upon utilization in ECDs delivered impressive electrochromic properties. A combination of features possessed by a particular device (QD-NR/PVDF-HFP/IL/BzV-Fc ECD) such as exceptionally low driving voltage (0.9 V), high transmittance change (ΔT, ∼69%), fast response time (∼1.8 s), high coloration efficiency (∼339 cm2/C), and remarkable cycling stability (∼90% ΔT-retention after 25,000 cycles) showcased a striking potential in the yet-to-realize market of GPE-based ECDs. This study unveils the untapped potential of choreographed nanofillers that can promisingly drive GPE-based ECDs to the doorstep of commercialization. |
URI: | https://scholars.lib.ntu.edu.tw/handle/123456789/640127 | ISSN: | 19448244 | DOI: | 10.1021/acsami.3c16506 |
顯示於: | 化學工程學系 |
在 IR 系統中的文件,除了特別指名其著作權條款之外,均受到著作權保護,並且保留所有的權利。