https://scholars.lib.ntu.edu.tw/handle/123456789/64957
Title: | 迷你乳化聚合製備次微米高分子功能性複合乳膠顆粒(1/3) Synthesis of Submicron Polymer Functional Complex Latex via Miniemulsion Polymerization |
Authors: | 邱文英 | Keywords: | thermoresponsive;superparamagnetic;N-isopropylacrylamide;inverse miniemulsion | Issue Date: | 25-May-2005 | Publisher: | 臺北市:國立臺灣大學化學工程學系暨研究所 | Abstract: | In this research, the thermoresponsive composite latex particles were prepared via W/O miniemulsion polymerization. Fe3O4 nanoparticles were homogeneously dispersed inside the poly(NIPAAm-co-MAA) latex particles. In the first step, PAA oligomers were used as the stabilizer to produce a stable water-based Fe3O4 ferrofluid, which could mix well with the water-soluble monomers. In the second step, the Fe3O4 / poly(NIPAAm-co-MAA) composite latex particles were synthesized via W/O miniemulsion polymerization. This polymerization proceeded in cyclohexane at room temperature with Span80 as the emulsifier, NIPAAm as thermoresponsive monomer, MAA as a comonomer with -COOH functional groups, and APS / SMBS as the redox initiator system. The distribution of Fe3O4 nanoparticles inside the composite latex particles was expected to be homogeneous. The nucleation and morphology of the composite latex particles were mainly controlled by the concentration of surfactant, Span80 in cyclohexane. The properties of the composite latex were examined with several instruments such as DSC and TGA. Finally, the superparamagnetic and thermoresponsive characteristics of this functional composite latex were also investigated. |
URI: | http://ntur.lib.ntu.edu.tw//handle/246246/9428 | Other Identifiers: | 932216E002013 | Rights: | 國立臺灣大學化學工程學系暨研究所 |
Appears in Collections: | 化學工程學系 |
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932216E002013.pdf | 572.67 kB | Adobe PDF | View/Open |
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