Two-step square wave testing: A 110-second method for diagnosing internal short circuit and two states of lithium-ion batteries
Journal
Journal of Energy Storage
Journal Volume
115
Start Page
116003
ISSN
2352-152X
Date Issued
2025-04-15
Author(s)
Po-Chung Cheng
Abstract
As batteries lose capacity over time, disposing of them presents substantial environmental and financial challenges. Regrouping retired batteries extends their life and reduces the need for new manufacturing costs. Regrouping necessitates evaluating performance indicators and identifying safety concerns, with prompt recognition of internal short circuits (ISC) helping lower the risk of thermal runaway and serious accidents. Current ISC detection techniques are time-consuming, generally requiring full charge-discharge cycles or extended relaxation periods for data collection. This study presents a quick diagnostic method that uses two consecutive unequal square waves over 110 s to simultaneously assess safety information and battery states. The duration and magnitude of each square wave are thoroughly discussed, where the first wave primarily identifies the two battery states, i.e., state of health (SOH) and state of charge (SOC), while the second wave with its associated impedance spectrum offers key insights for ISC detection. We employ machine learning techniques that draw on features from both waves: initial voltage and ohmic resistance from the first, and three low-frequency impedances from the second. This approach accurately classifies ISC severity levels with 93.83 % accuracy, while simultaneously predicting the SOH and SOC with root mean square errors of 2.22 % and 1.72 %, respectively.
Subjects
Internal short circuits
Lithium-ion battery
Machine learning
Square wave
State estimation
Publisher
Elsevier BV
Type
journal article