Tailoring linker defects in MOF-808 to improve CO2 separation in mixed matrix membranes
Journal
Journal of Membrane Science
Journal Volume
736
Start Page
124688
ISSN
03767388
Date Issued
2025-12
Author(s)
Abstract
Carbon capture is widely recognized as a pivotal technology for alleviating the accelerating impacts of global warming. Mixed matrix membranes (MMMs) that embed metal organic frameworks (MOFs) offer a compelling route to high-performance separations, and MOF-808 stands out among them because of its outstanding chemical stability and environmentally friendly synthesis. In this study, the defect density of MOF-808 was tuned by varying the formic acid modulator: Higher modulator loading produced MOF-808 with higher linker defect density. After synthesis, MOF-808 was washed with either water or ethanol and then incorporated into PEBAX matrix through a drying-free process that ensured uniform dispersion. Washing with ethanol altered the pore coordination environment of MOF-808, partially replacing formate with ethoxide. Introducing an appropriate amount of formic acid created additional open metal sites and increased both CO2 permeability and CO2/N2 selectivity; however, excessive formic acid produced too many defects, causing severe pore blockage and consequently lowering the CO2 permeability. The drying-free method, by preventing MOF aggregation and ensuring homogeneous dispersion, led to a 38 % increase in CO2/N2 selectivity compared with the conventional drying method. The ethoxide substitution induced by ethanol washing occupied part of the pore volume, leading to a reduction in CO2 permeability. The optimized MOF-808/PEBAX MMM achieved a CO2 permeability of 150 Barrer and a CO2/N2 selectivity of 76.4, both markedly higher than those of the pristine polymer. These results highlight a sustainable, scalable strategy for producing high-efficiency membranes for post-combustion CO2 capture.
Subjects
CO2 capture
Defect engineering
Metal-organic framework
Mixed matrix membranes
SDGs
Publisher
Elsevier B.V.
Type
journal article